Mean Free Path Calculator

Free Mean Free Path Calculator computes λ for gas molecules using molecular diameter and either number density or pressure & temperature.

864.6K uses Updated · 2026-05-12 Runs locally · zero upload
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How to Use Mean Free Path Calculator

  1. Pick input mode — diameter & n, or diameter, P, T.
  2. Enter diameter — pm, nm, or Å.
  3. Enter remaining values — n in m⁻³ or P & T in lab units.
  4. Read λ in metres alongside the derived number density.

Formula & Theory - Mean Free Path Calculator

λ = 1 / (√2 · π · d² · n)

Ideal-gas density (used when P,T are provided):
n = P / (kB · T)
kB = 1.380649 × 10⁻²³ J/K
SymbolMeaning
λMean free path (m)
dMolecular diameter (m)
nNumber density (m⁻³)
PPressure (Pa)
TAbsolute temperature (K)

Assumptions and Limits

  • Hard-sphere kinetic theory; real gases have softer potentials.
  • Single-species gas; mixtures need a weighted sum.

Use Cases for Mean Free Path Calculator

  • Vacuum science — Confirm molecular vs. viscous flow regimes.
  • Sputter coating — Estimate λ to choose chamber pressure.
  • Atmospheric physics — Compare λ across altitudes.
  • Education — Visualise kinetic theory predictions.

The Mean Free Path Calculator quickly bridges molecular diameter and macroscopic state.

Frequently asked questions about Mean Free Path Calculator

What is mean free path?

The average distance a molecule travels between collisions. The Mean Free Path Calculator implements the hard-sphere result λ = 1 / (√2 π d² n).

Which molecular diameter should I use?

Air ≈ 370 pm, N₂ ≈ 364 pm, H₂ ≈ 274 pm, He ≈ 260 pm. Use kinetic-theory effective diameters from your textbook for best results.

Why do I see very large λ in vacuum?

Low n → larger λ. At ultra-high vacuum, λ can reach meters or kilometers.

Is my data stored?

No. All calculations happen in your browser; nothing is sent to a server.